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Extra resources for Bretherick's Handbook of Reactive Chemical Hazards 2 vols set
Sample text
Detonation properties of gelled slurries of aluminium powder in aqueous nitrate or perchlorate salt solutions have been studied [3]. Reactions of aluminium powder with potassium chlorate or potassium perchlorate have been studied by thermal analysis [4]. For other combinations, See Halogens, above; Oxygen, below Ammonium peroxodisulfate: Aluminium, etc. 56/81 Zinc peroxide: Alone, or Metals See other REDOX REACTIONS 31 Oxygen 1. Phillips, B. R. , Combust. Flame, 1979, 35(3), 249—258 2. Ames Lab Yellow Alert 990217b, Internet, 1999 Metal powders or fibres ignite in an oxygen-fed resonance tube [1].
Chem. , 1943, 65, 1698 It is shock sensitive when dry. See other METAL AZIDE HALIDES, SILVER COMPOUNDS 0010. Silver chlorite [7783-91-7] AgClO2 Ag + O Cl O Alone, or Iodoalkanes Levi, G. , Gazz. Chim. Ital. [2], 1923, 53, 40 The salt is impact-sensitive, cannot be finely ground, and explodes at 105 C. Attempts to react silver chlorite with iodo-methane or -ethane caused explosions, immediate in the absence of solvents, or delayed in their presence. Hydrochloric acid, or Sulfur Mellor, 1941, Vol.
1966, 10, 334 3. Garin, D. L. , J. Chem. , 1970, 47, 741 4. Perrin, D. D. , Chem. , 1986, 22, 1084; Chem. Eng. News, 1987, 65(2), 2 Reclaimed silver nitrate crystals, damp with the alcohol used for washing, exploded violently when touched with a spatula, generating a strong smell of ethyl nitrate [1]. The explosion was attributed to formation of silver fulminate (which is produced on addition of ethanol to silver nitrate solutions). Ethyl nitrate may also have been involved. Alternatives to avoid ethanol washing of recovered silver nitrate are discussed [2], including use of 2-propanol [3].
